Trailblazer Tara Jones will referee the women's England-Wales match on Saturday in Perth.
Moore, widely regarded as England's best referee, and Chris Kendall are the two male English officials travelling for the tournament. Moore takes Papua New Guinea-France in Port Moresby, while Kendall handles Cook Islands-Fiji on Sunday.
NRL grand final referee Adam Gee will officiate Kangaroos-Kiwis; Ashley Klein returns after missing the NRL grand final.
NRL officials will handle the other opening-week games. Klein, Grant Atkins and Gerard Sutton also worked the NRL finals series, while Belinda Sharpe and Kasey Badger are also appointed.
For Gee, Klein and Atkins, the following names are the touch judges followed by the bunker official: Matt Noyen, Tyson Brough, Chris Butler; Kieren Irons, Daniel Luttringer, Chris Butler; Michael Wise, Jarrod Cole, Liam Kennedy.
In the same order, Sutton's officials are Dave Munro, Ziggy Przeklasa-Adamski and Ashley Klein; Kendall's are Jon Stone, Drew Oultram and Wyatt Raymond.
Badger's officials are Karra-Lee Nolan, Izzy Davidson and Peter Gough; Moore's are Geoffrey Poumes, Dillan Wells and Todd Smith.