Ben Te'o will coach the Australian men's Prime Minister's XIII, while Jillaroos coach Jess Skinner will lead the women's team.
Both sides will face Papua New Guinea's Prime Minister's XIII teams in Port Moresby on Saturday, October 3, 2026, the day before the NRL Grand Final in Sydney.
South Sydney Rabbitohs second-rower David Fifita will captain the men's squad, which also features Dragons twins Ryan and Toby Couchman, their teammate Hamish Stewart, and Bulldogs playmaker Lachlan Galvin.
The women's selections include Sharks fullback Jada Taylor, Cowboys lock Bree Chester and Dragons forward Ahlivia Ingram.
ARLC Executive Chairman Peter V'landys said: "The players selected are some of the best players in the game,"
He added: "Not only do they have the opportunity to represent their country, they will be ambassadors for Australia and for Rugby League. They will change lives for the better.
"On behalf of the Commission, I congratulate them on their selection."